You've run into a classic green-screen problem. To pull a proper key, you have to have decent separation between the subject and the green screen, so that none of the green bounces off the screen and spills onto the subject. Usually to achieve this you just move the subject further from the wall. But it's a lot harder to move your subject further off the floor!
How Hollywood handles this is by the time consuming process of rotoscoping. But I imagine that you don't want to go frame by frame manually coloring out the green spill.
For a solution that I haven't tried myself, but should work in theory is to paint the wall green, and the floor black. You would then pull both a Chroma Key, and a Luma Key on the same footage. The black would not reflect onto the subject, so the key should be cleaner. Your subject should not be wearing black shoes for this obviously. Might be worth a shot, but again this is theory only. If you do try it, come back to tell us how it worked (or didn't).
Hope this helps,
JB
John Burkhart
Editor-in-Chief
Videomaker